4.7 Article

Metal nanoparticle catalysts decorated with metal oxide clusters

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 81, Pages 10096-10098

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34885c

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Funding

  1. Institute for Catalysis in Energy Processes
  2. Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, U.S. Department of Energy [DE-FG02-03-ER15457]
  3. MRSEC program of NSF at the Materials Research Center [DMR-1121262]
  4. NSF Grant [CHE-9871268]
  5. NSF-NSEC
  6. NSF-MRSEC
  7. Keck Foundation
  8. State of Illinois
  9. Northwestern University

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Au nanoparticles decorated with mononuclear Ti-oxo units dispersed in silica clusters were formed by activating Au nanoparticles (similar to 2 nm) stabilized with Ti- and amine-functionalized siloxane oligomers. These Au nanoparticles were active catalysts for selective oxidation of propane to acetone, and the activity increased with increasing Ti density.

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