4.7 Article

Tetrabutylammonium iodide catalyzed allylic sulfonylation of α-methyl styrene derivatives with sulfonylhydrazides

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 100, Pages 12240-12242

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36960e

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Funding

  1. National Natural Science Foundation of China [21102130]

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Sulfonyl radicals generated from sulfonylhydrazides by the Bu4NI-tert-butyl hydroperoxide (TBHP) catalysis system underwent addition to a variety of alpha-methyl styrene derivatives to give the corresponding allylic sulfones. This selective allylic sulfonylation is metal-free, operationally simple, and environmentally friendly.

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