Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 100, Pages 12219-12221Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37510a
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Funding
- 973 Project'' [2012CB821704]
- NSFC [91122032, 90922009, 21121061]
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The large cryogenic magnetocaloric effect of a 3D oxydiacetate-bridged gadolinium-manganese MOF material, [Mn(H2O)(6)][MnGd(oda)(3)](2)center dot 6H(2)O (1), was evaluated by magnetization and heat capacity measurements. A maximum Delta S-m of 50.1 J kg(-1) K-1 for Delta H = 70 kG along with significant entropy change at lower field was found on account of the weak Mn center dot center dot center dot Gd ferromagnetic interactions and the small molecular mass. This suggests that 1 could be considered as a potential coolant for liquid helium temperature applications.
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