4.7 Article

Water-soluble ionic benzoporphyrins

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 55, Pages 6927-6929

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31057k

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Funding

  1. Miami University
  2. Ohio board of reagent
  3. US Air Force Office of Scientific Research [FA9550-10-1-0377]
  4. National Science Foundation [CHE-0840446, CHE0839233]
  5. Division Of Chemistry
  6. Direct For Mathematical & Physical Scien [1004875] Funding Source: National Science Foundation
  7. Division Of Chemistry
  8. Direct For Mathematical & Physical Scien [0840446] Funding Source: National Science Foundation

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Novel ionic water-soluble tetrabenzoporphyrins have been successfully synthesized via a cascade reaction based on the Heck reaction. The UV-Vis spectra of these porphyrins displayed red-shifted and broadened Soret bands, and significantly enhanced Q bands. These porphyrins are highly water soluble.

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