Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 61, Pages 7562-7564Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33321j
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Funding
- US National Science Foundation [CHE-0719267, CHE-1153085]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1153085] Funding Source: National Science Foundation
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The platinum butadiynyl complex trans-(C6F5)(p-tol(3)P)(2)Pt(C C)(2)H and a CuI adduct of a 1,10-phenanthroline based 33-membered macrocycle react in the presence of K2CO3 and I-2 or O-2 to give a rotaxane (ca. 9%) in which the macrocycle is threaded by the sp carbon chain of trans,trans-(C6F5)(p-tol(3)P)(2)Pt(C C)(4)Pt(Pp-tol(3))(2)(C6F5). The crystal structure and macrocycle/axle electronic interactions are analyzed in detail.
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