4.7 Article

Fluorescence photoswitching based on a photochromic pKa change in an aqueous solution

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 88, Pages 10874-10876

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35889a

Keywords

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Funding

  1. JSPS KAKENHI [23655111, 24685021]
  2. Grants-in-Aid for Scientific Research [23655111, 24685021] Funding Source: KAKEN

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Reversible fluorescence photoswitching of RSA-AZO dyad 1 was clearly demonstrated in an acidic aqueous solution. The fluorescence photoswitching mechanism is based on the reversible ring opening/closing reactions of the RSA unit induced by a photochromic pK(a) change along with the photoisomerization of the AZO unit.

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