Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 75, Pages 9370-9372Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34938h
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Funding
- National Science Foundation [CHE-0952370]
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Functionalization of the ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) has been realized with methoxy (H3BTB-[OMe](3)) and hydroxy (H3BTB-[OH](3)) groups. Combining H3BTB-[OMe](3) and Zn(II) results in the formation of the first isostructural, functionalized analogue of MOF-177 (MOF-177-OMe), while the combination of H3BTB-[OH](3) and Zn(II) generates a rare, interpenetrated pcu-e framework.
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