Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 39, Pages 4713-4715Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30799e
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Funding
- National Natural Science Foundation of China [21072145]
- Foundation for the Author of National Excellent Doctoral Dissertation of P.R. China [200931]
- Natural Science Foundation of Jiangsu Province of China [BK2009115]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Non-naturally enantioenriched cis-beta-thio-alpha-amino acid derivatives were synthesized through one pot, cascade thio-Michael/ring opening reaction of aromatic thiols with (Z)-olefinic azlactones in good yields with high levels of diastereoselectivities and enantioselectivities, which was catalyzed by a chiral bifunctional thiourea-tertiary amine catalyst.
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