Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 29, Pages 3545-3547Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17717j
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Funding
- National Natural Science Foundation of China [20932002, 21172076]
- National Basic Research Program of China (973 Program) [2011CB808600]
- Ministry of Education of China [20090172110014]
- Guangdong Natural Science Foundation [10351064101000000]
- Fundamental Research Funds for the Central Universities [2010ZP0003]
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The palladium-catalyzed and CsF-promoted annulation reaction of bromoalkynes and isocyanides regioselectively affords a diverse set of 5-iminopyrrolone derivatives. This chemistry presumably proceeds through the bromoacrylamide intermediates, which can be readily prepared from the nucleophilic addition reaction of isocyanides to bromoalkynes in the presence of CsF.
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