Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 72, Pages 9038-9040Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34676a
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Funding
- National Natural Science Foundation [U0932602, 90813004, 2009312311024]
- 973 Program [2009CB522300, 2011CB915503]
- State Key Laboratory of Phytochemistry and Plant Resources in West China [P2010-ZZ05]
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A novel sterically congested Lycopodium alkaloid named lycopalhine A (1) that possesses a fused hexacyclic (5/5/5/6/6/6) ring system comprising a 5,9-diaza-tricyclo[6.2.1.0(4,9)]undecane moiety and a tricyclo[5.2.1.0(4,8)]decane moiety was isolated from Palhinhaea cernua L. The structure and absolute configuration were determined by spectroscopic and computational methods.
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