Hydrogen shuttling: synthesis and reactivity of a 14-electron iridium complex featuring a bis(alkyl) tethered N-heterocyclic carbene ligand

Development of a Generic Mechanism for the Dehydrocoupling of Amine-Boranes: A Stoichiometric, Catalytic, and Kinetic Study of H3B·NMe2H Using the [Rh(PCy3)2]+ Fragment

(2012) Laura J. Sewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

(2011) Romaeo Dallanegra et al.   CHEMICAL COMMUNICATIONS

[Ir(PCy3)2(H)2(H2BNMe2)]+ as a Latent Source of Aminoborane: Probing the Role of Metal in the Dehydrocoupling of H3B⋅NMe2H and Retrodimerisation of [H2BNMe2]2

(2011) Charlotte J. Stevens et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium Complexes of the Doubly Cyclometalated NHC Ligand IMes′′

(2011) Janeth Navarro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing the Intrinisic Structure and Dynamics of Aminoborane Coordination at Late Transition Metal Centers: Mono(σ-BH) Binding in [CpRu(PR3)2(H2BNCy2)]+

(2011) Dragoslav Vidovic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

(2011) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination and Dehydrogenation of Amine-Boranes at Metal Centers

(2010) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Ammonia-Borane and Related Compounds as Dihydrogen Sources

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Sulfur-functionalized N-heterocyclic carbenes and their transition metal complexes

(2010) Matthias Bierenstiel et al.   COORDINATION CHEMISTRY REVIEWS

Amine− and Dimeric Amino−Borane Complexes of the {Rh(PiPr3)2}+Fragment and Their Relevance to the Transition-Metal-Mediated Dehydrocoupling of Amine−Boranes

(2010) Adrian B. Chaplin et al.   INORGANIC CHEMISTRY

Dehydrogenation of Saturated CC and BN Bonds at Cationic N-Heterocyclic Carbene Stabilized M(III) Centers (M = Rh, Ir)

(2010) Christina Y. Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes

(2010) Anne Staubitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes†

(2010) Gilles Alcaraz et al.   ORGANOMETALLICS

Rhodium and Iridium Aminoborane Complexes: Coordination Chemistry of BN Alkene Analogues

(2009) Christina Y. Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine-Boranes: Trapping of H2BNH2

(2009) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BH Activation at a Rhodium(I) Center: Isolation of a Bimetallic Complex Relevant to the Transition-Metal-Catalyzed Dehydrocoupling of Amine-Boranes

(2009) Adrian B. Chaplin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Mono-, Bi- and Tridentate N-Heterocyclic Carbene Ligands for the Preparation of Transition-Metal-Based Homogeneous Catalysts

(2009) Rosa Corberán et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Selective B-H versus N-H Bond Activation in Ammonia Borane by [Ir(dppm)2]OTf

(2009) Andrea Rossin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ammonia Borane as a Hydrogen Carrier: Dehydrogenation and Regeneration

(2009) Nathan C. Smythe et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Monomeric and Oligomeric Amine−Borane σ-Complexes of Rhodium. Intermediates in the Catalytic Dehydrogenation of Amine−Boranes

(2009) Thomas M. Douglas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination, Agostic Stabilization, and C−H Bond Activation of N-Alkyl Heterocyclic Carbenes by Coordinatively Unsaturated Ruthenium Hydride Chloride Complexes

(2009) Suzanne Burling et al.   ORGANOMETALLICS

Sterically Encumbered Iridium Bis(N-heterocyclic carbene) Systems: Multiple C−H Activation Processes and Isomeric Normal/Abnormal Carbene Complexes

(2009) Christina Y. Tang et al.   ORGANOMETALLICS

LabileN-Heterocyclic Carbene Complexes of Iridium

(2009) Olga Torres et al.   ORGANOMETALLICS

Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation

(2008) Vincent Pons et al.   CHEMICAL COMMUNICATIONS

B–N compounds for chemical hydrogenstorage

(2008) Charles W. Hamilton et al.   CHEMICAL SOCIETY REVIEWS