Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 97, Pages 11844-11846Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36169h
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Funding
- Deutsche Forschungsgemeinschaft [SFB 858]
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DNA double helices comprising two neighbouring artificial imidazole-Ag(I)-imidazole base pairs incorporate the Ag(I) ions in a cooperative fashion. Isothermal titration calorimetry data confirm the theoretically predicted binding stoichiometry and indicate that Ag(I) binds with association constants > 10(6) M-1 to the metal-free DNA duplex.
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