4.7 Article

Ion-pair triple helicates and mesocates self-assembled from ditopic 2,2'-bipyridine-bis(urea) ligands and Ni(II) or Fe(II) sulfate salts

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 60, Pages 7438-7440

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33062h

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Funding

  1. Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy

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NiSO4 and FeSO4 self-assemble with heteroditopic ligands (L) comprising 2,2'-bipyridine and o-phenylene-(bis)urea cation- and anion-binding sites, respectively, into [ML3SO4] (M = Ni2+, Fe2+) triple-stranded ion-pair helicates and mesocates.

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