Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 26, Pages 3167-3169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc00021k
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Funding
- MIUR [2009ZSC5K2_001, 20098SJX4F_004]
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The interconverting stereoisomers of tri-o-thymotide have been separated by HPLC on chiral stationary phases and the temperature dependence of the dynamic chromatographic patterns has been interpreted in terms of exchange between enantiomeric propeller and helical conformations. Computed low energy structures and CD spectra were used in absolute configuration assignment.
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