Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 100, Pages 12198-12200Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36926e
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The novel chlorogermyliumylidene complex L[ClGe:](+) (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a 'naked' Cl- as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe=S](+) cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.
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