Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 39, Pages 11137-11139Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14480d
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Funding
- National Natural Science Foundation of China [21032007, 21172038]
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A novel and efficient route for rapid access to indeno[1,2-c]azepin-3(2H)-ones is described, which proceeds through a palladium-catalyzed tandem reaction of 2-alkynylhalobenzene with 2-alkynylbenzamide in the presence of PPh(3) or PCy(3). The indeno[1,2-c] azepin-3(2H)-ones which incorporate both indene and unsaturated seven-membered ring lactam skeletons are obtained in good to excellent yields.
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