4.7 Article

An enantiopure Fe-4(III) single-molecule magnet

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 28, Pages 8049-8051

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12831k

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Funding

  1. NSFC [20821091, 90922033, 21071008]
  2. National Basic Research Program of China [2010CB934601]

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A pair of enantiopure star-shaped Fe-4(III) clusters were constructed from simple chiral ligands. AC field frequency dependence and a hysteresis loop, which are very important features of SMMs, were observed. Circular dichroism (CD) spectra demonstrated that the chirality was successfully transferred from the ligand to the coordination environment of Fe3+ ions.

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