Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 12, Pages 3634-3636Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05739h
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- Brandeis University
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The synthesis of a new pincer ligand containing a central cationic N-heterocyclic phosphenium donor is described. The electrophilic nature of this cationic ligand renders it non-innocent, and coordination of this ligand to a PtCl(2) fragment leads to chloride migration from Pt to the cationic phosphorus center.
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