Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 10, Pages 2835-2837Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03363d
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Funding
- NSF [CHE-0747481]
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Novel p-iodobenzoate-based labelling reagents are shown to be effective photocaged precursors for synthesizing biomolecular radicals site-selectively in the gaseous and condensed phases. In vacuo, a single pulse of UV photons (266 nm) is sufficient to quantitatively photolyse the C-I bond. In aqueous solutions, the photolysis half-life is estimated to be 2.5 minutes when irradiating with a 15 W compact fluorescent lamp (254 nm).
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