Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 27, Pages 7860-7862Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12047f
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Funding
- National Natural Science Foundation of China [NSFC-20976164]
- National Basic Research Program of China (973 Program) [2011CB710800]
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N-Heterocyclic carbene (NHC) catalyzed direct carbonylation of dimethylamine leading to the formation of DMF was successfully accomplished under metal-free conditions. The catalytic efficiency was investigated and the turnover numbers can reach as high as >300. The possible mechanism was also proposed.
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