4.7 Article

Decarboxylation of aromatic carboxylic acids by gold(I)-N-heterocyclic carbene (NHC) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 19, Pages 5455-5457

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10917k

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Funding

  1. EPSRC
  2. ERC
  3. Royal Society
  4. EPSRC [EP/H015418/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish

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A recently isolated gold(I) complex, [Au(IPr)(OH)], permits the transformation of carboxylic acids to the corresponding decarboxylated gold(I)-aryl complex without the use of silver co-catalyst under mild reaction conditions.

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