Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 35, Pages 9831-9833Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14072h
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- Ministry of Education, Science and Technology of Korea
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The increase in hydrogen back pressure unexpectedly enhances the overall dehydrogenation reaction rate of the 4LiBH(4) + YH3 composite significantly. Also, argon back pressure has a similar influence on the composite. Gas back pressure seems to enhance the dehydrogenation reaction by kinetically suppressing the formation of the diborane by-product.
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