4.7 Article

Colossal above-room-temperature metal-insulator switching of a Wadsley-type tunnel bronze

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 15, Pages 4484-4486

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05709f

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Funding

  1. National Science Foundation [DMR 0847169]
  2. American Chemical Society [50201DNI10]

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We show evidence of the manifestation of enormous metal-insulator switching ranging up to almost six orders of magnitude in individual nanowires of beta'-CuxV2O5. The magnitude and temperature of the phase transition is in strong contrast to data reported over several decades for other Wadsley-type mixed valence tunnel bronze structures.

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