Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 12, Pages 3416-3417Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc00087j
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Funding
- University of Hong Kong
- Research Grants Council of Hong Kong SAR [HKU 7011/08P]
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A concise, asymmetric synthesis of the pentacyclic framework of the cortistatins has been accomplished in 12 steps from commercially available starting materials, employing a highly diastereoselective intramolecular (4+3) cycloaddition of epoxy enolsilanes as the key step.
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