4.7 Article

Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene

Journal

CHEMICAL COMMUNICATIONS
Volume 47, Issue 35, Pages 9819-9821

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc13476k

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Funding

  1. MEXT, Japan
  2. PRESTO, JST

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The electron density of an alkyne moiety is enhanced by the photochromic ring closure of a diarylethene derivative, which allows the thermal addition reaction with a small pi-acceptor, tetracyanoethylene, at room temperature.

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