Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 15, Pages 4499-4501Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc10491h
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Funding
- Academy of Finland [KR 212588, 218325, PH 129772, MH 129171, 139571, MT 139571, JKT 134985]
- ESF
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The halogen bonding between [Ru(dcbpy)(2)(SCN)(2)] dye and I-2 molecule has been studied. The ruthenium complex forms a stable [Ru(dcbpy)(2)(SCN)(2)] center dot center dot center dot I-2 center dot 4(CH3OH) adduct via S ... I interaction between the thiocyanate ligand and the I-2 molecule. The adduct can be seen as a model for one of the key intermediates in the regeneration cycle of the oxidized dye by the I-/I-3(-) electrolyte in dye sensitized solar cells.
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