Journal
CHEMICAL COMMUNICATIONS
Volume 47, Issue 5, Pages 1632-1634Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04321d
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Funding
- NSFC [20772091, 20972110]
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An efficient, catalytic, diastereo- and enantioselective conjugate addition of N-(diphenylmethylene)glycine tert-butyl ester to beta-aryl substituted enones was realized in the presence of 1 mol% of newly desired dinuclear N-spiro-ammonium salts, affording functionalized alpha-amino acid derivatives in 57-98% yields with high diastereoselectivity (up to 99 : 1 dr) and enantioselectivity (up to 96.5 : 3.5 er).
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