4.7 Article

Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 14, Pages 2501-2503

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b923918a

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Funding

  1. Japan Society for the Promotion of Science

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The first asymmetric total synthesis of psychotrimine, a trimeric indole alkaloid, was accomplished via an asymmetric Ireland-Claisen rearrangement to construct a chiral quaternary carbon center, thereby establishing the absolute configuration of psychotrimine.

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