4.7 Article

A water reduction process performed by zinc metal under very mild conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 28, Pages 5115-5117

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00256a

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Funding

  1. Xunta de Galicia [INCITE09E2R209074ES]
  2. Ministerio de Educacion y Ciencia
  3. ERDF (EU) [CTQ2007-62185/BQU]

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Water reduction can be electrochemically promoted by zinc under very mild conditions, as demonstrated by the formation of the complex [Zn(H(2)O)(6)][Zn(3)(L)(3)(mu(3)-O)], whose anion consists of a Zn(3)O(4) cluster incorporating a mu(3)-oxo anion.

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