Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 29, Pages 5271-5273Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00294a
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- CNRS
- Region Nord-Pas de Calais
- Fonds Europeen de Developpement Regional (FEDER)
- Ministere de l'Education Nationale de l'Enseignement Superieur et de la Recherche
- Agence Nationale pour la Recherche [ANR-09-BLAN-0187-01]
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In this communication we report the synthesis and full structural characterization of the new phase Ba8Co2Mn6ClO22 formed of novel 8H-hexagonal perovskite blocks, a good example of the use of a multi-technique approach (combination of single crystal X-ray diffraction, micro-probe analysis and DFT calculations). Strikingly, the stabilization of original linear hexamers in the blocks is achieved by Mn/Co ordering in the octahedral and tetrahedral
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