4.7 Article

Reversible gating controlled by enzymes at nanostructured interface

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 12, Pages 2088-2090

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b927156b

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Funding

  1. National Science Foundation [DMR-0706209]
  2. ARO [W911NF-05-1-0339]
  3. Semiconductor Research Corporation [2008-RJ-1839G]
  4. Clarkson University

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A nanostructured biocatalytic interface reversibly gating electrochemical reactions upon chemical signals processed by immobilized enzymes was architectured. The chemical signals were converted to local interfacial pH changes causing restructuring of the stimuli-responsive polymer and switching ON-OFF the electrochemical reaction.

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