4.7 Article

Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 30, Pages 4557-4559

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b905150c

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Funding

  1. NSF
  2. ARO
  3. AFOSR
  4. DDRE
  5. NSSEF

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The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.

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