Article
Chemistry, Multidisciplinary
Norio Saito, Daiki Nishiyama, Yoshitaka Matsushita, Yoshiki Wada, Stephane Cordier, Takeo Ohsawa, Fabien Grasset, Naoki Ohashi
Summary: The study reports a reentrant phase transition of an organic-inorganic hybrid metal cluster compound, showing structural phase transitions from a conventional phase to an unknown phase at 143 K, and a reentrant transition to the conventional structure at 113 K. These transitions were characterized by slight motions of the MCs and TBA(+) ions, without any symmetry changes. Luminescence studies revealed a 1.7 times longer emission lifetime in the newly found phase compared to the conventional phase, indicating promising properties of MC-based compounds with phase transitions and crystallographic polymorphisms.
Article
Chemistry, Multidisciplinary
D. Ma, Y. Lan, D. Zhang, X. Qin, Z. Yang, H. He, X. Dai, Z. Ye, X. Cao
Summary: Organic-inorganic perovskite materials have shown excellent performance and competitiveness in high-performance photovoltaic and optoelectronic devices. Lead-halide perovskites with broadband emission have attracted interest for solid-state lighting, but their commercial exploitation is hindered by lead toxicity. In this study, a lead-free copper(I)-iodine hybrid was synthesized and its crystal structure and optical properties were investigated. The results show that this lead-free hybrid has potential applications in solid-state lighting and other perovskite opto-electronic devices.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Chemistry, Physical
Zixiao Qin, Jian He, Yin Zhu, Xiaopeng Wei, Jilin Wang, Guoyuan Zheng, Shuyi Mo, Bing Zhou, Fei Long
Summary: A new large-size two-dimensional organic-inorganic hybrid single crystal (C7H10N)2MnCl4 was synthesized using the solvent evaporation method. Crystal diffraction tests confirmed that it belongs to the Cc spatial group in the monoclinic system. Through Hirshfeld surface analysis and two-dimensional fingerprint analysis, it was found that the crystal mainly interacts through hydrogen bonds. The crystal exhibits good thermal stability and has the potential for impedance sensors based on its AC conductivity.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Article
Chemistry, Multidisciplinary
Hiroshi Takashima, Yoshiyuki Yoshida, Mitsuho Furuse
Summary: Superconducting pastes have been developed from superconducting particles, showing superconductivity, flexibility, adhesion, and ink properties in organic/inorganic hybrid compounds.
Article
Agronomy
Marlena Grzanka, Sylwester Smolen, Lukasz Skoczylas, Dominik Grzanka
Summary: Through experiments on maize, it was found that organic iodine compounds significantly increased iodine accumulation in maize grains, while the combination of a low dose of vanadium with KI and KIO3 increased iodine accumulation in leaves, roots, and grains. The combined application of vanadium in both doses with 2-IBeA most effectively stimulated the transport and accumulation of iodine to the maize grain.
Article
Crystallography
Bing Lei, Xin Wu, Wei Liu
Summary: An organic-inorganic hybrid structure based on copper (I) iodide staircase chain has been synthesized using a slow-diffusion method, showing red emission at 620 nm with an internal quantum yield of 6.5% under 360 nm excitation. This compound exhibits potential as a non-rare-earth light-emitting phosphor alternative.
Article
Chemistry, Applied
Yin-Qiang Zhang, Min Li, Guan-Cheng Xu
Summary: An In-based organic-inorganic hybrid compound, [C3H8N](3)InBr6 (1; C3H8N+ is cyclopropylammonium), has been successfully synthesized and experienced a reversible phase transition at 298 K, as confirmed by DSC measurement. Single-crystal X-ray diffraction revealed different crystal structures at 330 K and 240 K, indicating a disorder-order changes of the cyclopropylammonium cations causing the structural phase transition, with an obvious dielectric anomaly near the transition temperature. This work paves the way for further exploration and design of In-based organic-inorganic hybrid phase transition materials.
APPLIED ORGANOMETALLIC CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Qian-Qian Chen, Chun-Li Hu, Jin Chen, Yi-Lin Li, Bing-Xuan Li, Jiang-Gao Mao
Summary: An organic-inorganic hybrid polyiodate with a novel branched polyiodate chain structure has been successfully synthesized. This compound exhibits excellent Second-Harmonic-Generation (SHG) performance and a high laser-induced-damage-threshold (LIDT) under laser radiation, showing promising potential for applications.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Review
Chemistry, Multidisciplinary
Chumei Ye, Lauren N. McHugh, Celia Chen, Sian E. Dutton, Thomas D. Bennett
Summary: Crystalline materials have been crucial for the development of hybrid organic-inorganic perovskites (HOIPs), leading to interesting applications like solar cells and optoelectronic devices. Recently, the glassy state of HOIPs, which retains the basic building blocks of crystalline HOIPs but lacks long-range periodic order, has been discovered. The emerging family of glasses formed from HOIPs exhibit diverse properties complementary to their crystalline state. This mini review highlights the chemical diversity of 3D and 2D crystalline HOIPs and showcases the production of glasses from these materials, with a focus on achievements in melt-quenched glasses. Our perspective on the future of this new family of materials is also provided.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Materials Science, Multidisciplinary
Danyang Zhao, Qiancheng Zhu, Qiancheng Zhou, Wenming Zhang, Ying Yu, Shuo Chen, Zhifeng Ren
Summary: The redox couple of I-0/I- in aqueous rechargeable iodine-zinc (I-2-Zn) batteries shows promise as a safe, cost-effective, and steady energy storage resource. However, their cycle life and efficiency are hindered by uncontrolled polyiodide shuttling and side reactions on the Zn anode. By utilizing starch to confine polyiodide shuttling, the I-0/I- conversion efficiency of I-2-Zn batteries is significantly improved. This work provides inspiration for the rational design of high-performance and low-cost I-2-Zn batteries in aqueous zinc-ion batteries (AZIBs).
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Raja Azhar Saeed Khan, Jamal Kazmi, Bushra Ansari, Syed Raza Ali Raza, Nadia Tabbasum, Mohd Ambri Mohamed, Jamil Kazmi, Zamir-ul Hassan, Muhammad Naeem Ahmed, Asif Majeed, Syed Manzoor Hussain Bukhari
Summary: In this study, a two-terminal and broad spectral range organic-inorganic hybrid photodetector device is fabricated, which contains N-pentylisatin-based compound coated semiconducting Zinc oxide (ZnO) nanowires (NWs). The hybrid device shows extended range absorption and enhanced photosensitivity compared to the pristine device. The conductivity of the ZnO NWs thin film is greatly reduced after coating with N-pentylisatin, indicating the role of terminating oxygen molecules of N-pentylisatin as an electron acceptor.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Materials Science, Multidisciplinary
Wail Al Zoubi, Addul Wahab Allaf, Bassem Assfour, Young Gun Ko
Summary: A new strategy combining interface-plasma electrolysis and ultrahigh-vacuum physical vapor deposition has been developed to fabricate functionalized two-dimensional hybrid organic-inorganic (2D HOI) materials, demonstrating exceptional corrosion protection. Controlled growth of organic thin films based on reaction sites in organic molecules and the formation of flower-like structures upon contact with reactive solution facilitate corrosive penetration of the magnesium substrate. The theoretical calculations reveal a robust interaction between BTC molecules and the inorganic surface, contributing to the understanding of the organic-inorganic interfaces.
APPLIED MATERIALS TODAY
(2021)
Review
Chemistry, Physical
Afef Moulahia, Oussama Guesmia, Mohammed S. M. Abdelbaky, Santiago Garcia-Granda, Mohamed Dammale
Summary: A novel organic-inorganic hybrid compound based on iron fluoride has been synthesized and characterized. The compound, named C1, shows promising electrical and thermal properties, as confirmed by X-ray single-crystal diffraction, thermogravimetric analysis, differential scanning calorimetric, and dielectric measurements.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Biochemistry & Molecular Biology
Iwona Ledwozyw-Smolen, Joanna Pitala, Sylwester Smolen, Marta Liszka-Skoczylas, Peter Kovacik
Summary: Iodine is an essential microelement for human and animal organisms, and plant biofortification shows potential in improving iodine status. This study aimed to evaluate the efficiency of iodine uptake and accumulation in dandelion plants through a pot experiment. The plants were treated with inorganic (KI, KIO3) and organic forms (5-iodosalicylic acid, 5-ISA; 3,5-diiodosalicylic acid, 3,5-diISA) of iodine at different concentrations. Results showed that dandelion plants effectively absorbed both inorganic and organic forms of iodine without negative effects on growth. The highest efficiency in improving iodine content was observed with 50 μM KI, and the application of 5-ISA showed even higher iodine content compared to commonly used KIO3. It was also found that iodosalicylates are endogenous compounds in dandelion plants.
Article
Chemistry, Multidisciplinary
Qianwen Guan, Tingting Zhu, Zeng-Kui Zhu, Huang Ye, Shihai You, Peng Xu, Jianbo Wu, Xinyi Niu, Chengshu Zhang, Xitao Liu, Junhua Luo
Summary: In this study, a pair of unprecedented three-dimensional chiral halide perovskitoids was successfully synthesized, demonstrating unique chiroptoelectronic performance. The new material exhibited natural chiroptical activity and the ability to distinguish circularly polarized light, as well as sensitive X-ray detection performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Inorganic & Nuclear
Jack D. Evans, Bikash Garai, Helge Reinsch, Weijin Li, Stefano Dissegna, Volodymyr Bon, Irena Senkovska, Roland A. Fischer, Stefan Kaskel, Christoph Janiak, Norbert Stock, Dirk Volkmer
COORDINATION CHEMISTRY REVIEWS
(2019)
Article
Chemistry, Multidisciplinary
Patrice Kenfack Tsobnang, Emrah Hasturk, Dominik Frohlich, Emmanuel Wenger, Pierrick Durand, John Lambi Ngolui, Claude Lecomte, Christoph Janiak
CRYSTAL GROWTH & DESIGN
(2019)
Article
Materials Science, Multidisciplinary
Maryam Youhannayee, Saeideh Nakhaei-Rad, Fereshteh Haghighi, Karsten Klauke, Christoph Janiak, Mohammad Reza Ahmadian, Robert Rabenalt, Peter Albers, Mathias Getzlaff
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2019)
Article
Nanoscience & Nanotechnology
Philipp Brandt, Alexander Nuhnen, Marcus Lange, Jens Moellmer, Oliver Weingart, Christoph Janiak
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Nanoscience & Nanotechnology
Dennis Dietrich, Christopher Licht, Alexander Nuhnen, Simon-Patrick Hoefert, Laura De Laporte, Christoph Janiak
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Chemistry, Physical
Carsten Schluesener, Mergime Xhinovci, Sebastian-Johannes Ernst, Alexa Schmitz, Niels Tannert, Christoph Janiak
CHEMISTRY OF MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Franziska K. Merkt, Konstantin Pieper, Maximilian Klopotowski, Christoph Janiak, Thomas J. J. Mueller
CHEMISTRY-A EUROPEAN JOURNAL
(2019)
Article
Plant Sciences
Shuai Liu, Yuping Zhao, Christian Heering, Christoph Janiak, Werner E. G. Mueller, Sergi Herve Akone, Zhen Liu, Peter Proksch
JOURNAL OF NATURAL PRODUCTS
(2019)
Article
Plant Sciences
Ni P. Ariantari, Elena Ancheeva, Chenyin Wang, Attila Mandi, Tim-O. Knedel, Tibor Kurtan, Chaidir Chaidir, Werner E. G. Mueller, Matthias U. Kassack, Christoph Janiak, Georgios Daletos, Peter Proksch
JOURNAL OF NATURAL PRODUCTS
(2019)
Article
Nanoscience & Nanotechnology
Ilka Simon, Julius Hornung, Juri Barthel, Joerg Thomas, Maik Finze, Roland A. Fischer, Christoph Janiak
BEILSTEIN JOURNAL OF NANOTECHNOLOGY
(2019)
Article
Chemistry, Inorganic & Nuclear
Lucian Gabriel Bahrin, Dana Bejan, Sergiu Shova, Maria Gdaniec, Marek Fronc, Vasile Lozan, Christoph Janiak
Article
Chemistry, Inorganic & Nuclear
Vojtech Novohradsky, Gloria Vigueras, Jitka Pracharova, Natalia Cutillas, Christoph Janiak, Hana Kostrhunova, Viktor Brabec, Jose Ruiz, Jana Kasparkova
INORGANIC CHEMISTRY FRONTIERS
(2019)
Article
Chemistry, Multidisciplinary
Jie Hu, Tian Zhao, Wei Geng, Yi Lu, Xiao-Fang Zhao, Yuan-Zhou Li, Yu-Qian Tang, Jia-Wen Liu, Li-Ying Wang, Christoph Janiak, Xiao-Yu Yang, Bao-Lian Su
CHEMICAL COMMUNICATIONS
(2019)
Article
Chemistry, Inorganic & Nuclear
Simon Millan, Beatriz Gil-Hernandez, Erik Milles, Serkan Goekpinar, Gamall Makhloufi, Alexa Schmitz, Carsten Schluesener, Christoph Janiak
DALTON TRANSACTIONS
(2019)
Article
Chemistry, Physical
Marvin Siebels, Carsten Schluesener, Joerg Thomas, Yu-Xuan Xiao, Xiao-Yu Yang, Christoph Janiak
JOURNAL OF MATERIALS CHEMISTRY A
(2019)
Review
Chemistry, Multidisciplinary
Dan He, Yawen Li, Fuwen Zhao, Yuze Lin
Summary: High trap density in organic solar cells leads to localized charge carriers and reduced carrier lifetime, limiting device efficiency. This feature article summarizes the recent advances of trap suppression by material design and device engineering.
CHEMICAL COMMUNICATIONS
(2024)
Review
Chemistry, Multidisciplinary
Olivier Monfort, Arshitha Madhusudhan, Martin Motola
Summary: This article presents the advantages of coupling photocatalysis and Fenton-based processes for environmental remediation and discusses their synergy. It critically examines the simultaneous triggering of these two processes and provides insights into research approaches. The study aims to enhance understanding of this complex process and highlight the potential integration of new catalysts in current wastewater treatment technology.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Manideepa Dhar, Chittaranjan Mishra, Avijit Das, Uttam Manna
Summary: An approach of 'polymerization of monomers in its aggregated form' has been introduced to tailor the water wettability of fibrous and porous substrates, achieving hydrophobicity to superhydrophobicity transition, as well as patterned wettability. This facile chemical method provides a durable coating with adjustable and patterned wettability for various potential applications.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Saswat Ranjan Bhoi, Chhanda Debnath, Shikha Gandhi
Summary: In this article, a novel catalytic reaction using Pd(0) and Bronsted acid is reported for the synthesis of biologically important imidazolidinone-fused N-heterocycles through redox-neutral intramolecular N-allylation of indoles and pyrroles with alkynes. This atom-economical method is applicable to a wide range of substrates and eliminates the need for leaving groups or oxidizing agents commonly used in traditional allylation reactions.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Longkun Chen, Mingshuai Zhang, Meichen Liu, Zhuoyuan Liu, Yuetong Qiu, Zhilai Zhang, Fuchao Yu, Jiuzhong Huang
Summary: In this study, an efficient Rh(III)-catalyzed selective mono- and dual-C-H bond functionalization/cyclization with iodonium ylide as the sole coupling partner was demonstrated. Fused benzodiazepine skeletons were obtained in excellent yields, providing an improved approach to dual C-H unsymmetrical functionalization.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Alice Kennett, Sven Epple, Gabriella van der Valk, Irene Georgiou, Evelyne Gout, Romain R. Vives, Angela J. Russell
Summary: This study presents the design and synthesis of sulfated disaccharide inhibitors based on IdoA(2S)-GlcNS(6S), which showed potent inhibition of Sulf-2. The results suggest that IdoA(2S)-GlcNS(6S) is the shortest fragment size required for effective inhibition of Sulfs, and a trisulfated disaccharide is identified as the minimal fragment size of heparan sulfate for effective endosulfatase inhibition.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Mauro Garbini, Andrea Brunetti, Riccardo Pedrazzani, Magda Monari, Massimo Marcaccio, Giulio Bertuzzi, Marco Bandini
Summary: The self-adaptability of galvanostatic electrolysis was found to be helpful in a multistage chemo- and diastereoselective electrochemically promoted cyclodimerization of chalcones. Through a series of reductive events, densely functionalized cyclopentanes with five contiguous stereocenters were obtained (25 examples, yields up to 95%, dr values up to >20:1). Further experimental and electrochemical investigations indicated the crucial role of dynamic kinetic resolution of the aldol intermediate in the reaction mechanism.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Dhananjay S. Nipate, Neha Meena, Prakash N. Swami, Krishnan Rangan, Anil Kumar
Summary: In this study, the synthesis of functionalized benzo[a]phenazines and indazolo[2,3-a]quinolines was achieved through Rh(III)-catalyzed oxidative annulation of 2-arylquinoxalines and 2-aryl-2H-indazoles with allyl alcohols. The method showed a wide substrate scope, excellent functional group tolerance, good to high yields of annulated products, and the capability for scaled-up synthesis. A tentative mechanism of the annulation reaction was proposed based on a preliminary mechanistic investigation.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan
Summary: A new lead tellurium borate material with a unique fundamental building block [B4O10] was synthesized and found to exhibit high birefringence. The structure-property relationship was discussed using first-principles calculations.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Amresh Kumar Singh, Baishali Thakurta, Anupam Giri, Monalisa Pal
Summary: This study introduces three key concepts for the quick synthesis of large-scale high-quality 2D materials films and their utilization in device fabrication.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Reina Hagiwara, Shun Nishimura, Kosuke Okeyoshi
Summary: A copolymer-conjugated nanocatalytic system has been developed to improve electron transfer and enhance photoinduced H2 generation.
CHEMICAL COMMUNICATIONS
(2024)
