4.7 Article

Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 16, Pages 2142-2144

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b901943j

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Funding

  1. Universite catholique de Louvain
  2. Fonds pour la Recherche dans l'Industrie et l'Agriculture (F.R.I.A.)
  3. Fond de la Recherche Scientific
  4. Research Program of the Research Foundation-Flanders (FWO) [G.0464.06]

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The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent 5c have been developed.

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