4.7 Article

Active species of CeAl4 in the CeCl3-doped sodium aluminium hydride and its enhancement on reversible hydrogen storage performance

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 44, Pages 6857-6859

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b916898b

Keywords

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Funding

  1. National Basic Research Program of China [2007CB209701, 2010CB631300]
  2. National Natural Science Foundation of China [50871099, 50631020]
  3. China Postdoctoral Science Foundation [20080440196]
  4. New Century Excellent Talents in Universities [NCET-07-0741]

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By directly doping CeAl4 into sodium aluminium hydride, which probably serves as the active species in the hydriding and dehydriding processes of CeCl3-doped NaAlH4, a high reversible hydrogen capacity of 4.77-4.92 wt% (close to expected capacity of 5.13 wt%) can be achieved in less than 20 min under moderate conditions.

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