Journal
CHEMICAL COMMUNICATIONS
Volume -, Issue 38, Pages 4637-4639Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b804477e
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The enantioselective BINOL-phosphate catalyzed formation of a quaternary carbon center, bearing a N-atom has been achieved through the self-coupling reaction of enamides; the corresponding products have been isolated in up to > 99% ee and their application for the synthesis of versatile synthetic building blocks-beta-aminoketones-has been demonstrated.
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