4.7 Article

An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 43, Pages 5547-5549

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b813075b

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Funding

  1. National Natural Science Foundation of China
  2. Chinese Academy of Sciences

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The synthesis and structural characterization of an unprecedented lanthanide phosphinidene species [(THF)(3)(I)Nd-(mu-PC(6)H(3)-2,6-(i)Pr(2))](2) are described; the phosphinidene moiety in this complex reacts as a carbene.

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