Article
Chemistry, Organic
Daniel Timelthaler, Christoph Topf
Summary: This catalytic method allows for the pressure hydrogenation of quinolines in aqueous solution using a cobalt-based catalyst prepared from Co(OAc)(2)center dot 4H(2)O and zinc powder. The synthesis process is time-saving and operationally simple, with all reagents readily available from commercial sources. The reaction setup and autoclave charging are conducted outside an inert-gas-operated containment system for convenience.
SYNTHESIS-STUTTGART
(2022)
Article
Engineering, Chemical
Samuel Eshorame Sanni, Olowoyeye Philemon, Emeka Emmanuel Okoro, Babalola Aisosa Oni, Tijani A. Idowu, Oluwatosin Adegbite
Summary: Hydroconversion of 4-Chlorophenol was induced by atomic hydrogen substitution and polydisperse cobalt nanoparticles, resulting in enhanced reaction performance. The addition of NaOH as a proton scavenger effectively prevented catalyst deactivation. The 2 M polydisperse-cobalt nanoparticles showed the best performance with a k(eqd) value of 0.079, indicating successful desorption mechanism.
CHEMICAL ENGINEERING SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Ana Sousa-Castillo, Andrea Marino-Lopez, Begona Puertolas, Miguel A. Correa-Duarte
Summary: Bioorthogonal chemistry has provided a powerful tool for performing biocompatible chemospecific reactions in living systems, particularly in the areas of genetic encoding systems, bioimaging, and cancer therapy. This Minireview focuses on recent advances in the use of heterogeneous catalysts for bioorthogonal reactions, discussing the synthetic strategies of Pd-, Au-, and Cu-based materials, their applications in activating caged fluorophores and prodrugs, and the potential of using external stimuli for targeted drug release in diseased tissues. The review also highlights future directions and challenges in this emerging field.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Correction
Chemistry, Multidisciplinary
Sanny Verma, R. B. Nasir Baig, Mallikarjuna N. Nadagouda, Christophe Len, Rajender S. Varma
Summary: This study proposes a sustainable pathway to furanics from biomass via heterogeneous organo-catalysis.
Article
Engineering, Environmental
Dibyajyoti Panja, Sadhan Dey, Sabuj Kundu
Summary: Heterogeneous cobalt catalysts were synthesized and the catalyst with cobalt:phenanthroline ratio of 1:6 showed the highest activity. The selective degradation of azo compounds using various alcohols was effectively carried out. The catalyst could be recycled up to 6th times and the reaction was favorable for substrates with electron-donating substituents. Alcohol dehydrogenation was identified as one of the slow steps and ordered transition states were demonstrated.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Energy & Fuels
Indira Tobio-Perez, Yosvany Diaz Dominguez, Lizet Rodriguez Machin, Sven Pohl, Magin Lapuerta, Ramon Piloto-Rodriguez
Summary: Biodiesel production has increasingly shifted towards using heterogeneous catalysts derived from biomass, due to their sustainability, economical and eco-friendly nature, ease of recovery, and the potential to eliminate biomass residues. The review discusses various biomass sources as precursors for heterogeneous catalysts, different methods for preparation, their advantages and drawbacks, as well as their performance in biodiesel production. The use of biomass ash or biochar-based catalysts shows promise in biodiesel synthesis, but requires improvements in catalyst load, reaction time, temperature, and methanol-to-oil ratio.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Chemistry, Physical
Helapiyumi Weerathunga, Cheng Tang, Aidan J. Brock, Sarina Sarina, Tony Wang, Qiong Liu, Huai-Yong Zhu, Aijun Du, Eric R. Waclawik
Summary: Selective oxidation of alcohols is crucial for fine chemical production, and the photocatalytic oxidation of benzyl alcohol using ZnO nanocrystals was investigated in this study. Different shapes of ZnO nanocrystals displayed varying kinetics for the benzyl alcohol oxidation reaction, with nanocones showing the highest conversion rate. The {10 (1) over bar1} facet of ZnO was found to expose undercoordinated O atoms, leading to the highest adsorption of benzyl alcohol and ultimately resulting in 100% selectivity for benzaldehyde as the product.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Engineering, Environmental
Yiyang Ma, Bingxuan Ji, Xiaofan Lv, Dongbin Xiong, Xuesong Zhao, Haijiao Xie, Zhenghua Zhang
Summary: In this study, boron nitride (BN)-Co3O4 nanosheet cluster (NC) was fabricated to facilitate PMS activation for the rapid removal of ranitidine (RAN). The BN-Co3O4 NC showed highly efficient catalysis performance and could be applied in a wide pH range. The porous structure of BN-Co3O4 NC enhanced the catalytic performance by providing more channels for RAN and PMS molecules. PMS activation by BN-Co3O4 NC was mainly achieved through reduction via active radicals.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Xinyuan Lv, Miao Yu, Yali Guo, Minghao Sui
Summary: In this study, silver-doped cobalt ferrite catalysts were synthesized and used for the activation of peroxymonosulfate in the degradation of sulfamethoxazole. The results showed that Ag-0.06-CoFe2O4 exhibited the best catalytic activity and utilization efficiency, and the silver doping led to the exposure of more active sites and an increase in the concentration of oxygen vacancies.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Chemistry, Multidisciplinary
Yan Wan, Jong-Min Lee
Summary: The catalytic conversion of 5-hydroxymethylfufural (HMF) holds great promise for producing valuable chemicals and reducing dependence on fossil feedstocks. The reductive upgrading of HMF has shown potential to produce monomers and liquid fuel additives. Thermocatalytic conversion has advantages over photocatalysis and electrocatalysis in productivity. Research focuses on catalyst design, reaction conditions, and mechanisms.
Article
Chemistry, Multidisciplinary
M. Ronda-Leal, C. Espro, N. Lazaro, M. Selva, A. Perosa, S. M. Osman, A. Pineda, R. Luque, D. Rodriguez-Padron
Summary: Highly active, selective, and stable titania-based catalytic materials were synthesized using a simple and environmentally friendly microwave-assisted approach. The materials were further modified with metal nanoparticles using a simple chemical reduction method. The synthesized materials exhibited excellent catalytic performance in the reductive amination of furfural towards furfuryl amine, and showed remarkable recyclability after six reaction cycles.
MATERIALS TODAY CHEMISTRY
(2022)
Review
Chemistry, Multidisciplinary
Sebastien Noel, Bastien Leger, Anne Ponchel, Samahe Sadjadi, Eric Monflier
Summary: This review focuses on stabilizing catalytically active metal nanoparticles in cyclodextrin-based systems, where cyclodextrins play multi-functional roles as reducing agents, stabilizing/dispersing agents, and mass transfer promoters. The study also explores the design of more sophisticated catalytic systems with cyclodextrin as a supramolecular host in dynamic equilibrium.
ENVIRONMENTAL CHEMISTRY LETTERS
(2021)
Article
Engineering, Environmental
Jiangyong Liu, Rongfei Ye, Jie Shi, Haiyang Wang, Lixia Wang, Panming Jian, Dan Wang
Summary: The study presents a novel approach for the preparation of a Cu nanoparticles embedded nitrogen-doped carbon catalyst using cushaw and Cu salt, which shows promising catalytic performance in the liquid-phase reduction of nitrobenzene. Experimental and computational findings indicate the strong interaction between Cu nanoparticles and carbon layer, facilitating the adsorption and activation of NB molecules.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Zhijun Li, Xiaowen Lu, Rufang Zhao, Siqi Ji, Mingyang Zhang, J. Hugh Horton, Yang Wang, Qian Xu, Junfa Zhu
Summary: Researchers have developed an efficient molten-salt-assisted approach to create atomically dispersed cobalt atoms supported over vanadium pentoxide layered material. This cobalt single-atom catalyst achieves extraordinary catalytic efficiency in the dehydrogenative coupling reaction of alcohols and amines, with high selectivity and conversion. Density functional theory calculations confirm the optimized coordination environment and strong metal-support interaction contribute significantly to the activation of reactants.
Article
Chemistry, Multidisciplinary
Andrea Vassoi, Tommaso Tabanelli, Annalisa Sacchetti, Francesca Di Gioia, Luigi Capuzzi, Fabrizio Cavani
Summary: This study introduces a new heterogeneous catalyst for the oxidative cleavage of unsaturated fatty acids triglycerides derived from vegetable oil, providing a promising alternative to current ozonization processes. The catalyst based on Cu2+ showed efficient recovery, regeneration, and recycling capabilities, offering potential for further industrial exploitation.
Article
Chemistry, Physical
Ana Serrano-Lotina, Karen Cruz, Miguel A. Banares, Marco Daturi, Pedro Avila
Summary: Bimetallic shaped catalysts were prepared by wet equilibrium impregnation, where MnO2 was the main component and a second metal oxide (Co, Fe and Ce oxides) was added. The Ce-promoted catalyst showed the highest catalytic activity in the selective reduction of NOx with NH3 (88% NO conversion at 170 degrees C) due to its ability to adsorb NOx even in the presence of water. However, the Fe-promoted catalyst exhibited lower NOx conversion with NH3-SCR in the presence of water (65% NO conversion at 170 degrees C) due to the absence of NOx adsorbed species.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Ceramics
Rocio Estefania Rojas-Hernandez, Fernando Rubio-Marcos, Aida Serrano, Sara Roman-Sanchez, Jose Francisco Fernandez, Irina Hussainova
Summary: In this study, (hk0)-textured ZnAl2O4: Nd, Ce sub-micron films were synthesized using a screen printing technique assisted by a molten salt flux and deposited over the sapphire substrate. The focus was on controlling the Ce concentration in the emitting layers and determining the key parameters for the development of efficient ZnAl2O4-based films with remarkable optical properties. The degree of crystallinity and precise adjustment of texture were found to be crucial for improving NIR luminescence efficiency. Specifically, (hk0)-textured films developed at a sintering temperature of around 1300 degrees C exhibited higher NIR emission intensity compared to (hkl)-untextured films. This research demonstrates a feasible approach to achieve high NIR emission performance and validates its applicability for a wide range of applications.
CERAMICS INTERNATIONAL
(2023)
Review
Chemistry, Physical
Aida Serrano, Olga Caballero-Calero, Cecilia Granados-Miralles, Giulio Gorni, Cristina Manzano, Marta Rull-Bravo, Alberto Moure, Marisol Martin-Gonzalez, Jose F. Fernandez
Summary: This study demonstrates the use of a cold sintering process (CSP) to sinter CoSb3-based thermoelectric materials for the first time. The CSP yields samples with a relative density of 86% at 150℃ with a uniaxial pressure of 750 MPa, which is increased to around 92% after a post-annealing at temperatures ≥ 500℃ in Ar atmosphere. The CSP produces Te doped-CoSb3 nanocomposites with similar morphological and structural characteristics to the starting nanopowders obtained by ball milling in air atmosphere. The sintered thermoelectric nanocomposites exhibit a maximum figure of merit of 0.12(3) at room temperature.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Ali Saffar Shamshirgar, Maria Fernandez Alvarez, Adolfo del Campo, Jose Francisco Fernandez, Rocio E. Rojas Hernandez, Roman Ivanov, Johanna Rosen, Irina Hussainova
Summary: This study incorporates graphene-augmented alumina nanofibers into epoxy resin to fabricate a tunable absorption multilayer structure for electromagnetic interference shielding and RF absorption. Highly aligned graphene augmented alumina nanofibers were produced using a hot wall one-step catalyst-free chemical vapor deposition method. The highest loss tangent of 0.4 was achieved in a composite containing 1 vol% of randomly oriented nanofibers. A superposed three-layer structure was fabricated, offering an absorption of >90% in the entire X-band and an absorption peak of -25 dB at around 11 GHz. The hybrid nanofibers with a dual loss function show potential for versatile design options in RF absorption.
Article
Biochemistry & Molecular Biology
Elizabeth Rojas Garcia, Gloria Perez-Soreque, Ricardo Lopez Medina, Fernando Rubio-Marcos, Ana M. M. Maubert-Franco
Summary: In this study, CNTs/Fe-BTC composite materials were synthesized using a one-step solvothermal method, with MWCNTs and SWCNTs incorporated in situ during synthesis. The composite materials were characterized and found to exhibit improved physical-chemical and optical properties compared to Fe-BTC pristine. The incorporation of CNTs into Fe-BTC not only showed higher production rates, but also changes in selectivity. Furthermore, the incorporation of CNTs allowed for increased electron mobility, decreased charge carrier recombination, and increased photocatalytic activity. These composite materials showed promise in converting CO2 to clean fuels that could replace fossil fuels soon.
Article
Chemistry, Applied
M. Olga Guerrero-Perez, Olga B. Lapina, Soren B. Rasmussen, Miguel A. Banares
Summary: Nanoscaled-VPO catalysts were prepared on an alumina support to achieve high surface-to-volume ratio of the active phase. Surface species transformations were studied using these nanoscaled catalysts, with minimized signal from the bulk. The chemical environment and oxidation state of the species were determined by NMR, ESR, and XANES spectroscopies. The results optimized V + P coverage and V/P molar ratio to minimize isolated vanadium oxide species and maximize V4+ concentration. The distribution of phosphorus islands greatly influenced the structure of the catalytic material for the desired partial oxidation reaction.
TOPICS IN CATALYSIS
(2023)
Article
Nanoscience & Nanotechnology
Victor Fuertes, Adolfo del Campo, Nicolas Gregoire, Philippe Labranche, Jose Francisco Fernandez, Younes Messaddeq
Summary: An in-depth study of nanoparticle-doped optical fibers using confocal Raman microscopy, Rayleigh light-scattering microscopy, and scanning electron microscopy (SEM) reveals the crystallization structures and size-dependent Raman shifts of YPO4 nanocrystals in the fiber core. The study also evaluates the Raman properties of the nanocrystals at different temperatures, observing linear phonon softening behavior. These findings provide new insights into the characteristics of nanoparticle-doped optical fibers and open up possibilities for further research in this field.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Electrical & Electronic
Mauro Difeo, Fernando Rubio-Marcos, Adolfo Del Campo, Miriam Castro, Leandro Ramajo
Summary: Sodium bismuth titanate based lead-free piezoceramics with modified dielectric and energy storage properties were obtained by doping Nb. The doping of Nb changes the material structure and microstructural characteristics, resulting in a transition from multiphasic coexistence to a single phase, and improving the piezoelectric response and energy storage properties of the material.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Materials Science, Multidisciplinary
A. Moure, P. Val-Gomez, A. del Campo, J. F. Fernandez, F. Rubio-Marcos
Summary: In this study, the stress dynamics and its temperature dependence arising from the Orthorhombic-Tetragonal Polymorphic Phase Boundary (PPB) in lead-free potassium sodium niobate (KNN)-based ceramics were investigated. The growth of Orthorhombic phases is limited by the high-temperature tetragonal phase distributions, and two main mechanisms regulate the decrease of stress processes: microstructural effects hinder the formation of non-180° domains, while ferroelectric domain distribution and local structural heterogeneity contribute to the phase transition widening.
MATERIALS & DESIGN
(2023)
Article
Instruments & Instrumentation
Alessio Sacco, Luisa Mandrile, Li-Lin Tay, Nobuyasu Itoh, Ankit Raj, Alberto Moure, Adolfo Del Campo, Jose F. Fernandez, Keith R. Paton, Sebastian Wood, Hyuksang Kwon, Tehseen Adel, Angela R. Hight Walker, Erlon Henrique Martins Ferreira, Ralf Theissmann, Thomas Koch, Andrea Mario Giovannozzi, Chiara Portesi, Andrea Mario Rossi
Summary: This article presents an interlaboratory comparison on Raman spectroscopy as a reliable method for quantification of TiO2 phases. Raman spectroscopy is a fast, non-invasive technique that can differentiate and measure TiO2 without the need for special reagents or sample preparation.
Article
Construction & Building Technology
Jacqueline Roberta Tamashiro, Miguel Angel de la Rubia, Fernando Rubio-Marcos, Rocio Estefania Rojas-Hernandez, Lucas Henrique Pereira Silva, Fabio Friol Guedes de Paiva, Angela Kinoshita, Amparo Moragues Terrades
Summary: This study comprehensively explores the impact of ZnO particle morphology on cement hydration. It is found that ZnO nanoparticles can delay the hydration process, while ZnO microparticles can enhance mechanical properties.
JOURNAL OF BUILDING ENGINEERING
(2023)
Article
Chemistry, Physical
Rocio E. Rojas-Hernandez, Fernando Rubio-Marcos, Jallouli Necib, Mati Danilson, Jose F. Fernandez, Irina Hussainova
Summary: Near-infrared (NIR) emitting phosphors are in high demand for their applications in various fields. This study focuses on synthesizing ZnAl2O4:Ce/Nd films of nanometer thickness for NIR emission using a cost-efficient approach. The use of polycrystalline alumina substrates enhances emission intensity. The concentration of Ce4+ influences NIR emission. The findings contribute to understanding film production processes and guide future studies on NIR emitters.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Biochemistry & Molecular Biology
I. Mena-Prado, J. J. Reinosa, M. Fernandez-Garcia, J. F. Fernandez, A. Munoz-Bonilla, A. del Campo
Summary: In this study, biobased composite materials based on poly(lactic acid) (PLA) and poly(butylene adipate-co-tera-phthalate) (PBAT) were developed for antibacterial and compostable food packaging films. The incorporation of sodium hexametaphosphate microparticles (E452i) as antimicrobial filler and acetyl tributyl citrate (ATBC) as plasticizer improved the thermal stability, crystallinity, and mechanical properties of the films. The E452i particles also provided antimicrobial properties against Listeria innocua and Staphylococcus aureus, with bacterial reduction percentages higher than 50% in films with 5 wt% of particles. The films maintained their disintegradability under industrial composting conditions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Engineering, Environmental
S. Marin-Cortes, M. Fernandez-Alvarez, A. Moure, J. F. Fernandez, E. Enriquez
Summary: This study proposes a method for quantifying mixed construction materials through homogenization and chemometric modeling. It successfully applies this method to real CDW samples, enhancing their recycling potential in the ceramic industry and promoting CDW valorization and sustainability.
RESOURCES CONSERVATION AND RECYCLING
(2023)