Journal
CHEMCATCHEM
Volume 5, Issue 12, Pages 3680-3689Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201300448
Keywords
fuel cells; nanoparticles; platinum; ruthenium; supported catalysts
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Funding
- Spanish Ministry of Science and Education [ENE2010-15381, CTQ2010-17338]
- Comunidad Autonoma de Madrid [S2009/ENE-1743]
- CSIC [2007801017]
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The modification of mesoporous carbon black with polypyrrole (C-PP) facilitates the incorporation of homogeneously dispersed nanosized Ru-Pt particles (1-2nm) onto the support. Polypyrrole-modified carbon supports were prepared by the addition of different amounts of pyrrole, followed by insitu polymerization through oxidative treatments. The Ru-Pt/C-PP electrocatalysts were tested in the oxygen-reduction reaction in methanol-containing acidic electrolytes by using both conventional electrochemical techniques and in a direct methanol single cell. The performance of Ru-Pt/C-PP was far superior to that of Pt/C for the oxygen-reduction reaction in the direct methanol fuel cell. Under severe methanol-crossover conditions, the maximum power density that was delivered by Ru-Pt/C-PP after degradation tests was decreased by 20%, whereas that of Pt/C decreased by 75%. Thus, the presence of Ru oxides in the cathode led to more tolerant electrocatalysts towards the presence of methanol in the reaction medium during the oxygen-reduction reaction.
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