Journal
CHEMCATCHEM
Volume 3, Issue 2, Pages 343-346Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201000295
Keywords
alcohols; chemoenzymatic synthesis; hydrolases; one-pot synthesis; polymer-bound reagents
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Funding
- Romanian National Council of Scientific Research of Higher Education (BD CNCSIS) [384]
- Romanian Ministry of Education and Research (CNCSIS) [527/2461]
- European Commission
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
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Both enantiomers of various 1-aryl-1,2-ethanediols have been prepared in a one-pot method from the corresponding arylethanones through the combination of chemical and enzymatic reactions. A range of aryl groups, phenyl, 4-chlorophenyl, benzo[b]thiophene-3-yl, and benzofuran-2-yl, were used. The highly enantiomerically enriched (R)- and (S)-1-aryl-1,2-ethanediols were obtained with excellent yields, calculated for the arylethanones.
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