4.7 Article

Effect of silicon carbide particle size and CaO content on foaming properties during firing and microstructure of porcelain ceramics

Journal

CERAMICS INTERNATIONAL
Volume 40, Issue 8, Pages 12931-12938

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2014.04.153

Keywords

Firing; Porosity; SiC; Anorthite

Funding

  1. National Natural Science Foundation of China [50872034]
  2. Major Scientific and Technological Projects of Guangdong Province [2010A080405004]
  3. Applied Basic Research Program of Guangzhou [2012J4100006]
  4. Project on the Integration of Industry, Education and Research of Guangdong Province [2012B091100451]
  5. Project on the Integration of Industry, Education and Research of Chancheng District [2012B1023]

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Porcelain green bodies were prepared using porcelain stoneware tile powder as the major raw material, with silicon carbide (SiC) and CaO as additives. These were fired at 1000-1200 degrees C. The effects of SiC particle size and CaO content on the microstructure and foaming properties of porcelain ceramics were investigated in detail, with a view to further clarify the dominant factors linking foaming behavior to SiC oxidation during firing of a porcelain tile matrix. The results reveal that the size of the SiC particles has a significant influence on the number, size, and interconnectivity of the pores formed in the samples; this effect becomes more pronounced as the SiC particle size is reduced. The addition of a small amount of CaO is shown to significantly accelerate the foaming of a porcelain green body containing SiC, but this effect is gradually inhibited by an increasing formation of anorthite Finally, the foaming mechanism is also discussed in detail. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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