4.7 Article Proceedings Paper

Influence of Ca substitution on microstructure and electrical properties of Ba(Zr,Ti)O3 ceramics

Journal

CERAMICS INTERNATIONAL
Volume 39, Issue -, Pages S35-S39

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2012.10.031

Keywords

Dielectric properties; Diffusion; Piezoelectric properties

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In the present work, lead-free (Ba1-xCax)(Zr0.04Ti0.96)O-3 (x=0.00-0.09) ceramics were fabricated via a solid-state reaction method. The microstructure and electrical properties of the ceramics were investigated. The microstructure of the BCZT ceramics showed a core shell structure at compositions of x=0.03 and 0.06. The substitution of small amount of Ba2+ by Ca2+ resulted in an improvement of the piezoelectric, dielectric and ferroelectric properties of the ceramics. The orthorhombic-tetragonal phase transition was found in the composition of x <= 0.03. Piezoelectric coefficient of d(33)similar to 392 pC/N and lowest E-c similar to 3.3 kV/cm with highest P-r similar to 14.1 mu C/cm(2) were obtained for the composition of x=0.03 while its Curie temperature (T-C) was as high as 125 degrees C. However, the ferroelectric to paraelectric transition temperature had slightly shifted towards room temperature with increasing Ca2+ concentration. (C) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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