4.7 Article

Blue light emission from barium doped zinc sulfide nanoparticles

Journal

CERAMICS INTERNATIONAL
Volume 38, Issue 7, Pages 5497-5500

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2012.03.063

Keywords

Semiconductors; Optical absorption; Band gap; Photoluminescence

Funding

  1. MHRD, Govt. of India

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ZnS nanoparticles with Ba(2+)doping have been prepared at room temperature through chemical route, namely the chemical precipitation method. The nanostructures of the prepared nanoparticles have been analyzed using X-ray diffraction (XRD) for phase analysis, Field emission scanning electron microscope (FESEM) for the morphological characterization, UV-Vis-NIR spectrophotometer for determining band gap energy and fluorescence spectroscopy for determining the emission wave length. The sizes of as prepared nanoparticles are found to be in 9-10 nm range. FESEM morphology shows the formation of nanostructure of ZnS samples. The value of optical band gap has been found to be in range 4.10-4.63 eV. Room temperature photoluminescence (PL) spectrum of the undoped sample exhibits emission in the blue region with multiple peaks under UV excitation. On the other hand, the Ba2+ doped ZnS samples exhibit visible light emissions under the same UV excitation wavelength of 310 nm. (c) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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