Article
Materials Science, Ceramics
Shalini Rajpoot, Jang-Hoon Ha, Young-Wook Kim
Summary: The mechanical, thermal, and electrical properties of porous SiC ceramics can be independently tuned by selecting the appropriate starting particle size and sintering atmosphere. In the porosity range of 40% to 54%, the compressive strength and thermal conductivity of porous SiC ceramics increased as the porosity increased, contrary to the general trend. Additionally, the electrical conductivity of porous SiC ceramics sintered in N-2 atmosphere was significantly higher compared to those sintered in Ar atmosphere due to N doping in the PCS-derived beta-SiC.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Shalini Rajpoot, Rohit Malik, Young-Wook Kim
Summary: Introducing multiple heterogeneous interfaces in ceramics can increase thermal resistance efficiently. The novel porous SSAT ceramics exhibited significantly lower thermal conductivity compared to porous monolithic SiC, SiO2, Al2O3, and TiO2 ceramics at an equivalent porosity, with the lowest thermal conductivity achieved at 74% porosity being 0.059 W/(m.K). The specific compressive strength value of the porous SSAT ceramics at 74% porosity was 3.2 MPa cm(3)/g.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Xianxi Li, Liwen Yan, Anran Guo, Haiyan Du, Feng Hou, Jiachen Liu
Summary: Silica-alumina composite porous ceramics with high porosity and low thermal conductivity were prepared by the particle-stabilized foaming method. They have the potential to serve as thermal insulation material in the spacecraft industry.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Xianxi Li, Liwen Yan, Yibo Zhang, Xukun Yang, Anran Guo, Haiyan Du, Feng Hou, Jiachen Liu
Summary: The demand for high-performance lightweight thermal insulation materials in reusable spacecraft and vehicles has led to the development of porous silica ceramics with lightweight, ultra-low thermal conductivity, and enhanced compressive strength. By using different sizes of silica particles, the compressive strength and pore structure integrity of the ceramics were improved. These ceramics have a very low thermal conductivity and are suitable for use as thermal insulation materials in aerospace and space applications.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Qiao Xu, Xianglei Liu, Qingyang Luo, Yang Tian, Chunzhuo Dang, Haichen Yao, Chao Song, Yimin Xuan, Junming Zhao, Yulong Ding
Summary: This study proposes an eco-friendly SiC ceramic based on loofah-derived materials for efficient solar thermal energy storage. After impregnation with NaCl-NaF eutectics, the ceramic demonstrates broadband solar absorption, rapid thermal transport, and compact latent heat storage.
ENERGY STORAGE MATERIALS
(2022)
Article
Materials Science, Ceramics
Wenyan Huang, Yufeng Wang, Zhonghao Ning, Shengjian Mao, Zhichao Xue, Yeqi Zhu, Qianwen Tao, Siqi Lan, Rongqian Yao
Summary: An ingenious strategy is reported to produce lightweight SiC composite ceramics with good load-bearing and remarkable surficial antioxidant capacity by reactively repyrolyzing flexible polymolybdenumcarbosilane-vinyltriethoxysilane-graphene oxide fillers blends. Highly cross-linked precursors connect up to five polycarbosilane to optimize their formability. In-situ formed MoSi2 and Mo4.8Si3C0.6 effectively strengthen interface bonding, promote crack formation, and hinder grain growth. The use of in-situ SiC nanowires by a Mo-containing catalyst further reinforces the ceramic network and improves the mechanical properties.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Zhenfei Chai, Zhaohe Gao, Han Liu, Xun Zhang, Gyorgyi Glodan, Ping Xiao
Summary: The study found that sintering temperature and sintering additive content have significant effects on the microstructure and thermal conductivity of SiC ceramics. Increasing sintering temperature promotes grain growth, while higher sintering additive content results in smaller grain size and lower thermal conductivity.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
Shynar Kultayeva, Young-Wook Kim, In-Hyuck Song
Summary: The study found that doping significantly affects the properties of porous SiC ceramics, with electrical resistivity strongly influenced by doping while thermal and mechanical properties primarily dependent on the necking area between grains. Results show that the electrical conductivity of porous SiC ceramics can be successfully tuned independently of the thermal conductivity through suitable doping.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
Yeqi Zhu, Chao Jin, Zhonghao Ning, Wenyan Huang, Shengjian Mao, Zhichao Xue, Siqi Lan, Qianwen Tao, Rongqian Yao
Summary: This study proposes a flexible strategy to prepare porous Mo4.8Si3C0.6/SiC(rGO) polymer-derived ceramics via re-pyrolysis of ball-milling-induced MoSi2-SiC(rGO)(p) precursors blends. The in-situ formed Mo4.8Si3C0.6-beta-SiC nanocrystals and dense Mo4.8Si3C0.6-beta-SiC/SiOxCy/C-free(rGO) framework contribute to the high porosity and increased hardness/fracture toughness. The samples exhibit excellent mechanical properties and low thermal conductivity, while maintaining good structural integrity and oxidation resistance.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Ceramics
Jeong-Ah Yeom, Young-Wook Kim, Wook Ki Jung, Dong-Ik Cheong, Eul Son Kang
Summary: This study investigated the effects of B4C content on the specific stiffness, mechanical properties, and thermal properties of pressureless-sintered SiC ceramics. SiC ceramics with 2.5 wt% C and 0.7-20 wt% B4C as sintering aids were successfully sintered to over 99.4% of theoretical density at 2150 degrees C in Ar. The specific stiffness of SiC ceramics increased from 136.1 x 106 to 144.4 x 106 m2 & BULL;s- 2 as the B4C content increased from 0.7 to 20 wt%.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Zhaoxin Zhong, Biao Zhang, Jian Ye, Ye Gao, Qiang Liu, Zhiguo Zhang, Feng Ye
Summary: In this study, porous SiC/Ti3SiC2 ceramic composites were prepared with enhanced electrical conductivity through nano-laminated Ti3SiC2, and achieved good thermal conductivity through in-situ formed nano beta-SiC and raw coarse alpha-SiC in the porous ceramics. The permeability, thermal, and electrical conductivity of the porous SiC/Ti3SiC2 ceramics were improved by adjusting the initial alpha-SiC particle size.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Lei Han, Xiaojian Li, Faliang Li, Haijun Zhang, Xueyin Liu, Guangqiang Li, Quanli Jia, Shaowei Zhang
Summary: High strength SiC reinforced Si3N4 ceramics aerogels were fabricated using foam-gelcasting and catalytic reaction, exhibiting excellent thermal conductivity and specific strength. The additional reinforcement from SiC whiskers formed in the Si3N4 matrix enhanced the mechanical properties of the aerogels.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Q. Xu, X. Liu, Q. Luo, Y. Song, H. Wang, M. Chen, Y. Xuan, Y. Li, Y. Ding
Summary: This study presents a strategy for ultrafast solar and thermal energy storage based on biomorphic SiC skeletons embedded NaCl-KCl molten salts, achieving a record-high thermal conductivity through replicating cellular structure of oak wood. By decorating TiN nanoparticles on SiC skeletons, the solar absorptance is enhanced, enabling designed composites to have bifunctional capabilities of harvesting both thermal energy and solar energy very rapidly.
MATERIALS TODAY ENERGY
(2021)
Article
Materials Science, Ceramics
Wenyan Huang, Jiahao Liang, Kun Zhuang, Shengjian Mao, Yinong Zheng, Yeqi Zhu, Qianwen Tao, Rongqian Yao
Summary: An ingenious strategy based on the repyrolysis process of ball-milling-induced fillers/precursors has been proposed for the preparation of porous SiC(rGO) bulk polymer-derived ceramics (PDCs) for thermal protection. The materials exhibit good load-bearing capacity and thermal insulation, especially in the porous SiC(rGO) PDCs with 10 wt% PS content, which have low thermal conductivity, excellent fracture toughness, outstanding hardness, optimal compressive strength, and good flexural strength.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Ceramics
Yinong Zheng, Ke Li, Wenyan Huang, Yuchen Han, Siqi Lan, Jiahao Hu, Zhenguo Huang, Chao Jin, Yinggan Zhang, Rongqian Yao
Summary: This study successfully prepared SiC(rGO, Gx) bulk polymer-derived ceramics using a unique synthesis route, exhibiting excellent performance with high electrical and thermal conductivities. The method is conducive to mass production and potential emerging uses.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
G. Amirthan, M. Balasubramanian
CERAMICS INTERNATIONAL
(2015)
Article
Materials Science, Ceramics
Mangesh Lodhe, Narendra Babu, A. Selvam, M. Balasubramanian
JOURNAL OF ADVANCED CERAMICS
(2015)
Article
Materials Science, Ceramics
Mangesh Lodhe, A. Selvam, A. Udayakumar, M. Balasubramanian
CERAMICS INTERNATIONAL
(2016)
Article
Nanoscience & Nanotechnology
Mangesh Lodhe, Niraj Chawake, Devinder Yadav, M. Balasubramanian
SCRIPTA MATERIALIA
(2016)
Article
Materials Science, Composites
N. Kavitha, M. Balasubramanian, A. Xavier Kennedy
JOURNAL OF COMPOSITE MATERIALS
(2013)
Article
Chemistry, Multidisciplinary
J. Chandradass, M. Balasubramanian, Ki Hyeon Kim
JOURNAL OF EXPERIMENTAL NANOSCIENCE
(2011)
Article
Materials Science, Multidisciplinary
A. Udayakumar, M. Stalin, M. B. Abhayalakshmi, Ramya Hariharan, M. Balasubramanian
JOURNAL OF NUCLEAR MATERIALS
(2013)
Article
Engineering, Manufacturing
J. Chandradass, M. Balasubramanian, Dong Sik Bae, Hern Kim
MATERIALS AND MANUFACTURING PROCESSES
(2012)
Article
Chemistry, Inorganic & Nuclear
B. Praveen Kumar, H. H. Kumar, D. K. Kharat, M. Balasubramanian, B. S. Murty
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
(2014)
Article
Engineering, Mechanical
G. Amirthan, M. Balasubramanian
Editorial Material
Metallurgy & Metallurgical Engineering
M. Balasubramanian, K. C. Hari Kumar, V. Subramanya Sarma, K. Ravi Sankar
TRANSACTIONS OF THE INDIAN INSTITUTE OF METALS
(2013)
Article
Polymer Science
P. Prabhu, P. Jawahar, M. Balasubramanian, T. P. Mohan
INTERNATIONAL JOURNAL OF POLYMER SCIENCE
(2013)
Article
Nanoscience & Nanotechnology
Ummen Sabu, C. N. Shyam Kumar, G. Logesh, Mohammed Rashad, Georgian Melinte, Anand Joy, Christian Kuebel, M. Balasubramanian
Summary: The research investigated the formation of alpha-Al2O3 platelets using eggshell membranes as bio-templates, highlighting the crucial role of biomacromolecules and functional groups present on the eggshell membrane. The growth of alpha-Al2O3 platelets was carefully studied using scanning and transmission electron microscopes, leading to a proposed growth mechanism involving the eggshell membrane. This study offers insights for the development of alpha-Al2O3 anisotropic structures through a bio-templated approach.
SCRIPTA MATERIALIA
(2021)
Article
Materials Science, Ceramics
G. Logesh, Mangesh Lodhe, M. Balasubramanian
CERAMICS INTERNATIONAL
(2017)
Proceedings Paper
Engineering, Manufacturing
N. Kavitha, M. Balasubramanian, Y. Deval Vashistha
MATERIAL AND MANUFACTURING TECHNOLOGY II, PTS 1 AND 2
(2012)