4.7 Article

The ternary system Portland cement-calcium sulphoaluminate clinker-anhydrite: Hydration mechanism and mortar properties

Journal

CEMENT & CONCRETE COMPOSITES
Volume 32, Issue 7, Pages 497-507

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.cemconcomp.2010.03.010

Keywords

Ordinary Portland cement; Calcium sulphoaluminate cement; Calcium sulphate; Hydration; Mortar

Funding

  1. University of Bern (Switzerland)

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Binders composed of ordinary Portland cement (OPC), calcium sulphoaluminate clinker (CSA) and anhydrite (C (S) over bar) were examined in order to study the impact of variations of the OPC:CSA:C (S) over bar ratio on the hydration process and related mortar properties. A first sample series had various anhydrite contents and fixed OPC to CSA ratio, and a second various OPC contents and fixed CSA to C (S) over bar ratio. Experiments made on pastes and thermodynamic modelling showed that the phase assemblage formed during the hydration of the binders was not very sensitive to changes in modal composition, while the ettringite to monosulphoaluminate volume ratio was influenced. All mixes started to hydrate with the formation of ettringite during a reaction involving C(4)A(3)(S) over bar and calcium sulphate. This generated high early strength. Until about 7 d, mainly the CSA clinker reacted, and 15-20% of the dry binder was converted to ettringite. From about 7 d on, the OPC clinker phase alite reacted significantly, stratlingite, C-S-H and monosulphoaluminate formed, while the ettringite content decreased. According to the laboratory experiments, the CSA clinker was mainly responsible for the early mechanical properties, while OPC played an important role at later ages. (C) 2010 Elsevier Ltd. All rights reserved.

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