Journal
CATALYSIS LETTERS
Volume 130, Issue 3-4, Pages 463-469Publisher
SPRINGER
DOI: 10.1007/s10562-009-9976-0
Keywords
Photooxidation; Immobilized alumina; Hydroquinone-like ligand; 5-Sulfosalicylic acid
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Selective oxidation of benzene with H2O2 to phenol has been developed using a novel Fe(III) complex bearing 5-sulfosalicylic acid ligands immobilized alumina catalyst under visible light irradiation. The catalyst activity was evaluated by the photooxidation of benzene to phenol. The results indicate the best result with 100% conversion of benzene and 27.64% selectivity for phenol at low catalyst loading (0.7 mmol/g alumina). The catalyst was used for at least 4 cycles without any appreciable loss of activity.
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