Article
Chemistry, Applied
Teng-ge Mi, Yang-wen Wu, Xin-yue Zhou, Wen-tao Li, Li Zhao, Ji Liu, Qiang Lu
Summary: The study investigates the mechanisms of carbon monoxide (CO) oxidation on two SCR catalyst models and finds that the CO oxidation cycle consists of two key stages. The activation energy for CO oxidation on V2O5/TiO2 surface is lower than that on V2O5-WO3/TiO2, indicating that WO3 doping inhibits the CO oxidation.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Materials Science, Ceramics
Desheng Feng, Ming Li, Sze Long Yee, Yang Jiang, Mao Chen, Yi Peng, Xiaodong Ma
Summary: The study conducted high-temperature phase equilibrium experiments on V2O5-Fe2O3 and V2O5-TiO2 systems, revealing that quenching of V2O5-containing systems should not be done using water-based media. Phase diagrams were constructed for both systems and compared with previous studies, improving upon existing results and providing a foundation for thermodynamic modelings and future applications in both systems.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Engineering, Environmental
Yong Yin, Xiang Li, Kezhi Li, Runqi Liu, Haina Wu, Tianle Zhu
Summary: Regeneration of spent V2O5-WO3/TiO2 catalysts, especially those containing hazardous As, is highly desirable. A formic acid-mediated regeneration strategy has been developed to achieve superior catalytic activity, short timescale regeneration, and recycling of nontoxic metallic As. The optimal regenerated catalyst shows 98.3% activity of the fresh catalyst with 99.1% As removal and less than 1.8% V loss within 15 minutes.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Physical
Dongrun Xu, Weiye Qu, Junhong Liu, Junxiao Chen, Xue Fang, Liwei Chen, Zhen Ma, Xi Liu, Xingfu Tang, Yaxin Chen
Summary: This study provides evidence that dinuclear vanadium-tungsten sites are the most active catalytic sites in conventional V2O5-WO3/TiO2 SCR catalysts, contrary to the prevailing view. These sites have stronger acidity and higher concentration of vanadium 3d electrons, leading to improved NH3 adsorption and O-2 activation in SCR. This finding settles a long-standing dispute and has important implications for understanding SCR mechanisms and designing better catalysts.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Environmental Sciences
Ajit Dattatray Phule, Joo Hong Choi, Jin Hyoung Kim
Summary: NOx emissions from stationary and mobile sources are a major global environmental issue, with selective catalytic reduction (SCR) using V2O5-WO3/TiO2 (VWT) catalyst being the most effective technique for reducing these emissions. Manganese has been found to be the best substitute for vanadium in the VWT catalyst, improving catalytic efficiency and maintaining stable NO conversion performance. The addition of manganese in the 3Mn3V9WT powder catalyst enhances NO conversion performance, with NH3 leakage below 20ppm and NOx conversion reaching 95-98% at temperatures between 260-320 degrees Celsius.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Min Seong Lee, Sun- Kim, Bora Jeong, Jin-Woo Park, Taehyo Kim, Jung Woo Lee, Gibum Kwon, Duck Hyun Lee
Summary: Research on coating an NH4+ layer on a vanadium-based catalyst can significantly improve its NOX removal efficiency over a wide temperature range, as well as enhance its proton conductivity, reducing the amount of vanadium oxides and tungsten oxide.
Article
Chemistry, Physical
Wei Zhao, Kai Zhang, Licheng Wu, Qian Wang, Danhong Shang, Qin Zhong
Summary: This study evaluates the effect of self-doping Ti3+ into catalysts on the activity of the catalysts. Various characterization methods such as XRD, XPS, and EPR confirm the presence of Ti3+ and oxygen vacancy, which significantly affect the performance of the catalysts. The results indicate potential for improving low-temperature SCR performance through strategic design of Ti3+ self-doped catalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Applied
Thi Phuong Thao Nguyen, Ki Hyuck Yang, Moon Hyeon Kim, Yong Seok Hong
Summary: The Fe2O3-promoted V2O5-WO3/TiO2 catalysts showed good N-2 selectivity and suppression of N2O formation in the NH3-SCR reaction. However, an increase in Fe2O3 loading led to a decrease in high-temperature deNOx activity. Surface reactions between N2O and strongly adsorbed NH3 species on the catalysts could greatly suppress N2O formation, starting from as low as 250 degrees C.
Article
Chemistry, Physical
Ruonan Wang, Yanli Zhang, Xing Fan, Jian Li
Summary: In this study, novel low-temperature SCR catalysts were developed by regulating the pH value and doping cobalt based on a V2O5-MoO3/TiO2 (VMT) catalyst. The results showed an increased SCR performance with 82.8% and 91.1% for catalysts after pH (=10) modification (VMT-10) and (1 wt%) Co/pH (=10) modification (1CoVMT-10), respectively. Various characterization techniques confirmed that the pH regulation transformed polymerization V species into isolated V5+=O, thus enhancing the NH3 and NO2 adsorption capacity.
Article
Environmental Sciences
Yili Zhang, Yongchun Zhao, Zhuo Xiong, Tian Gao, Rihong Xiao, Pengfei Liu, Jing Liu, Junying Zhang
Summary: The study showed that V2O5/TiO2 and Ce-doped catalysts have both thermo- and photo-catalytic reactivities in removing elemental mercury, with Ce doping significantly improving the mercury removal properties of the catalyst.
Article
Green & Sustainable Science & Technology
Hyun Soo Lee, Jae Hwan Yang, Hyun Ji Lee, Hyojin Lee, Sang-Chae Jeon
Summary: This study introduces a novel preparation method for synthesizing V2O5-TiO2 nanocatalysts to enhance desulfurization performance, resulting in increased specific surface area and improved interactions between V and Ti, leading to enhanced catalytic activities in the selective oxidation of H2S. The study emphasizes the importance of preparation conditions in manipulating the physicochemical properties and performances of catalysts.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Chemistry, Physical
Martin Elsener, Rob Jeremiah G. Nuguid, Oliver Krocher, Davide Ferri
Summary: Research has shown that formaldehyde in exhaust gases can react with NH3 to produce HCN, leading to a parasitic consumption of NH3 and a decrease in NOx conversion rate by up to 15%. Additionally, the non-reducible TiO2 support also produces moderate levels of HCN, indicating that redox sites enhance the reaction.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Multidisciplinary
Min Seong Lee, Yeong Jun Choi, Su-Jeong Bak, Mingyu Son, Jeehoon Shin, Duck Hyun Lee
Summary: Efficient selective catalytic reduction (SCR) catalysts were prepared using the polyol process, showing high nitrogen oxide (NOx) removal efficiency at low temperatures. The catalysts also had smaller particle size, which increased surface area and catalytic acid sites.
Article
Engineering, Environmental
Jae Hwan Yang, Hyun Ji Lee, Hyun Soo Lee, Sang-Chae Jeon, Young-Soo Han
Summary: The results suggested that the catalyst heat-treated at 400 degrees C under N-2 atmosphere (N-400) exhibited excellent catalytic performance for H2S removal, with high H2S conversion and sulfur yield. The study highlighted the importance of precisely controlled heat-treatment to enhance catalytic activity for H2S removal.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
L. Lv, S. Wang, Z. Zhang, L. Wang, P. He
Summary: Supported Ru catalysts with various crystal phases of TiO2 were prepared and their catalytic activities for CH3Br complete oxidation were investigated. The catalyst Ru/TiO2-700-4 showed the highest activity among others. The lower lattice mismatch and stronger metal support interaction between RuO2 and rutile TiO2 on the surface contributed to the enhanced catalytic performance. The mixed-phase TiO2 also promoted the dispersion of RuO2 and epitaxial growth, resulting in higher activity. The catalytic activity was influenced by the physico-chemical properties of Ru active sites, electron transfer, and surface acidity.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Zihao Wang, Junsheng Wu, Jia Li, Xiaoguang Wu, Yunhua Huang, Xiaogang Li
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE
(2018)
Article
Physics, Condensed Matter
Aoni Xu, Chaofang Dong, Xin Wei, Yanxian Zhang, Xiaogang Li
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2018)
Article
Chemistry, Physical
Wei Wu, Xuequn Cheng, Huaxing Hou, Bo Liu, Xiaogang Li
APPLIED SURFACE SCIENCE
(2018)
Article
Chemistry, Physical
Decheng Kong, Chaofang Dong, Zhaoran Zheng, Feixiong Mao, Aoni Xu, Xiaoqing Ni, Cheng Man, Jizheng Yao, Kui Xiao, Xiaogang Li
APPLIED SURFACE SCIENCE
(2018)
Article
Chemistry, Physical
Cheng Man, Chaofang Dong, Zhongyu Cui, Kui Xiao, Qiang Yu, Xiaogang Li
APPLIED SURFACE SCIENCE
(2018)
Review
Materials Science, Multidisciplinary
Yingchao Li, Dake Xu, Changfeng Chen, Xiaogang Li, Ru Jia, Dawei Zhang, Wolfgang Sand, Fuhui Wang, Tingyue Gu
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2018)
Article
Materials Science, Multidisciplinary
Xuequn Cheng, Yi Wang, Xiaogang Li, Chaofang Dong
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2018)
Article
Materials Science, Multidisciplinary
Kui Xiao, Pan Yi, Chaofang Dong, Shiwen Zou, Xiaogang Li
Article
Nanoscience & Nanotechnology
Wenkui Hao, Zhiyong Liu, Wei Wu, Xiaogang Li, Cuiwei Du, Dawei Zhang
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2018)
Article
Chemistry, Physical
Xin Wei, Chaofang Dong, Aoni Xu, Xiaogang Li, Digby D. MacDonald
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2018)
Article
Materials Science, Coatings & Films
Fan Zhang, Hongchang Qian, Luntao Wang, Zhou Wang, Cuiwei Du, Xiaogang Li, Dawei Zhang
SURFACE & COATINGS TECHNOLOGY
(2018)
Article
Materials Science, Multidisciplinary
Yuwei Ye, Dawei Zhang, Zhiyong Liu, Wei Liu, Haichao Zhao, Liping Wang, Xiaogang Li
Article
Engineering, Mechanical
Yuwei Ye, Zhiyong Liu, Wei Liu, Dawei Zhang, Yongxin Wang, Haichao Zhao, Liping Wang, Xiaogang Li
TRIBOLOGY INTERNATIONAL
(2018)
Review
Chemistry, Multidisciplinary
Ruilin Xiong, Kui Xiao, Pan Yi, Yuting Hu, Chaofang Dong, Junsheng Wu, Xiaogang Li
Article
Materials Science, Multidisciplinary
Decheng Kong, Chaofang Dong, Mifeng Zhao, Xiaoqing Ni, Cheng Man, Xiaogang Li
CORROSION ENGINEERING SCIENCE AND TECHNOLOGY
(2018)