Journal
CATALYSIS LETTERS
Volume 127, Issue 3-4, Pages 348-353Publisher
SPRINGER
DOI: 10.1007/s10562-008-9687-y
Keywords
n-Hexane; Ethanol; HZSM-5; Coupled reaction; Mechanism
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The coupled reaction of n-hexane and ethanol over HZSM-5 zeolite has been, for the first time, investigated with a pulse-reaction system. The catalytic reaction results showed an improvement of the initial conversion activity of n-hexane when ethanol was introduced as co-reactant. The FT-IR analysis revealed that the ethanol molecules adsorbed on Bronsted acidic sites were immediately transformed into surface ethoxy groups, which were active species for converting n-hexane and improving the initial conversion activity of n-hexane by a bimolecular hydride transfer mode. Also, the catalytic tests suggested that alkenes resulting from the transformation of ethanol could not enhance the initial conversion of n-hexane compared to active ethoxy groups at the shortest contact time. A mechanism involving the ethoxy groups was proposed to understand the coupled reaction of ethanol and n-hexane.
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