Journal
CATALYSIS COMMUNICATIONS
Volume 12, Issue 3, Pages 202-206Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2010.09.009
Keywords
Amines; Imines; Oxidative coupling; Metalloporphyrins
Categories
Funding
- National Natural Science Foundation of China [21036009, 20976203]
- China Postdoctoral Science Foundation [20080440792]
- Fundamental Research Funds for the Central Universities
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Highly efficient oxidative coupling of amines to amines by tert butyl hydroperoxide (t-BuOOH) in the presence of metalloporphyrins has been reported Manganese porphyrin showed excellent activity and selectivity for the oxidative coupling of amines to imines under ambient conditions Moreover a plausible mechanism involving high valence oxo intermediate has been proposed (C) 2010 Elsevier B V All rights reserved
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