☆ 4.6 Article

Sulfonic acid functionalized mesoporous SBA-15 for one-pot synthesis of substituted aryl-14H-dibenzo xanthenes and bis(indolyl) methanes

CATALYSIS COMMUNICATIONS (2010)

Journal

CATALYSIS COMMUNICATIONS

Volume 11, Issue 14, Pages 1148-1153

Publisher

ELSEVIER SCIENCE BV

DOI: 10.1016/j.catcom.2010.06.004

Keywords

Xanthenes; Bis (indolyl) methanes; SBA-15; Heterogeneous catalysis

Categories

Chemistry, Physical

Funding

Birla Institute of Science and Technology
DST (Department of Science and Technology-New Delhi, Govt. of India)
CSIR (Council of Scientific and Industrial Research)

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Abstract

The comparative catalytic activity studies of biologically and industrially important compounds such as Xanthenes and bis (indolyl) methanes were evaluated over propylsulfonic acid functionalized SBA-15/SO(3)H. The material was characterized via standard characterization techniques such as Powder X-ray diffraction, FTIR. Temperature programmed desorption studies of NH(3). The catalytic performance of SBA/SO(3)H under environmentally benign conditions results in high yield of xanthenes compared to bis (indolyl) methanes and finally the mechanism for both the reactions were proposed. (C) 2010 Elsevier B.V. All rights reserved.

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